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dc.contributor.authorWaters, Jessica E.
dc.contributor.authorBerger, Georg
dc.contributor.authorPeel, Andrew J.
dc.contributor.authorGarcía Rodríguez, Raúl 
dc.contributor.authorBond, Andrew D.
dc.contributor.authorWright, Dominic Simon
dc.date.accessioned2021-10-25T12:43:30Z
dc.date.available2021-10-25T12:43:30Z
dc.date.issued2021
dc.identifier.citationChemistry - A European Journal, 2021, vol. 27, n. 47. p. 12036-12040es
dc.identifier.issn1521-3765es
dc.identifier.urihttps://uvadoc.uva.es/handle/10324/49359
dc.descriptionProducción Científicaes
dc.description.abstractSupramolecular main group chemistry is a developing field which parallels the conventional domain of metallo-organic chemistry. Little explored building blocks in this area are main group metal-based ligands which have the appropriate donor symmetry to build desired molecular or extended arrangements. Tris(pyridyl) main group ligands (E(py)3, E=main group metal) are potentially highly versatile building blocks since shifting the N-donor arms from the 2- to the 3-positions and 4-positions provides a very simple way of changing the ligand character from mononuclear/chelating to multidentate/metal-bridging. Here, the coordination behaviour of the first main group metal tris(4-pyridyl) ligands, E(4-py)3 (E=Sb, Bi, Ph−Sn) is explored, as well as their ability to build metal-organic frameworks (MOFs). The complicated topology of these MOFs shows a marked influence on the counter anion and on the ability of the E(4-py)3 ligands to switch coordination mode, depending on the steric and donor character of the bridgehead. This structure-directing influence of the bridgehead provides a potential building strategy for future molecular and MOF design in this area.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subject.classificationCoordination networkses
dc.subject.classificationRedes de coordinaciónes
dc.subject.classificationPnictogenses
dc.subject.classificationPnictógenoes
dc.subject.classificationTripodal ligandses
dc.subject.classificationLigandos tripodaleses
dc.subject.classificationTopologyes
dc.subject.classificationTopologíaes
dc.titleUncovering the hidden landscape of Tris(4-pyridyl) ligands: Topological complexity derived from the bridgeheades
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holder© 2021 Wileyes
dc.identifier.doi10.1002/chem.202101291es
dc.relation.publisherversionhttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202101291es
dc.peerreviewedSIes
dc.description.projectLeverhulme Trust (grant RPG-2017-146)es
dc.description.projectMinisterio de Economía, Industria y Competitividad - Agencia Estatal de Investigación - Fondo Social Europeo (contract RYC-2015-19035)es
dc.description.projectMinisterio de Ciencia, Innovación y Universidades - Agencia Estatal de Investigación - Fondo Europeo de Desarrollo Regional (grant PGC2018-096880-A-I00)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


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