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dc.contributor.authorLozano Martín, Daniel 
dc.contributor.authorVega Maza, David
dc.contributor.authorMoreau Ortega, Alejandro
dc.contributor.authorMartín González, María del Carmen 
dc.contributor.authorTuma, Dirk
dc.contributor.authorSegovia Puras, José Juan 
dc.date.accessioned2021-11-04T08:06:32Z
dc.date.available2021-11-04T08:06:32Z
dc.date.issued2021
dc.identifier.citationThe Journal of Chemical Thermodynamics, 2021, vol. 158, 106434es
dc.identifier.issn0021-9614es
dc.identifier.urihttps://uvadoc.uva.es/handle/10324/49619
dc.descriptionProducción Científicaes
dc.description.abstractThis work aims to address the technical aspects related to the thermodynamic characterization of natural gas mixtures blended with hydrogen for the introduction of alternative energy sources within the Power-to-Gas framework. For that purpose, new experimental speed of sound data are presented in the pressure range between (0.1 up to 13) MPa and at temperatures of (260, 273.16, 300, 325, and 350) K for two mixtures qualified as primary calibration standards: a 11 component synthetic natural gas mixture (11 M), and another low-calorific H2-enriched natural gas mixture with a nominal molar percentage . Measurements have been gathered using a spherical acoustic resonator with an experimental expanded (k = 2) uncertainty better than 200 parts in 106 (0.02%) in the speed of sound. The heat capacity ratio as perfect-gas γpg, the molar heat capacity as perfect-gas Cp,mpg, and the second βa and third γa acoustic virial coefficients are derived from the speed of sound values. All the results are compared with the reference mixture models for natural gas-like mixtures, the AGA8-DC92 EoS and the GERG-2008 EoS, with special attention to the impact of hydrogen on those properties. Data are found to be mostly consistent within the model uncertainty in the 11 M synthetic mixture as expected, but for the hydrogen-enriched mixture in the limit of the model uncertainty at the highest measuring pressures.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherElsevieres
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subject.classificationSpeed of soundes
dc.subject.classificationSonido, Velocidad deles
dc.subject.classificationAcoustic resonancees
dc.subject.classificationResonancia acústicaes
dc.subject.classificationHydrogenes
dc.subject.classificationHidrógenoes
dc.subject.classificationNatural gases
dc.subject.classificationGas naturales
dc.titleSpeed of sound data, derived perfect-gas heat capacities, and acoustic virial coefficients of a calibration standard natural gas mixture and a low-calorific H2-enriched mixturees
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holder© 2021 Elsevieres
dc.identifier.doi10.1016/j.jct.2021.106434es
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S0021961421000495?via%3Dihubes
dc.peerreviewedSIes
dc.description.projectFondo Europeo de Desarrollo Regional - Ministerio de Ciencia, Innovación y Universidades (project ENE2017-88474-R)es
dc.description.projectFondo Europeo de Desarrollo Regional - Junta de Castilla y León (project VA280P18)es
dc.description.projectMinisterio de Ciencia, Innovación y Universidades (fellowship BEAGAL18/00259)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


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