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    Título
    Sunlight-driven AO7 degradation with perovskites (La,Ba)(Fe,Ti)O3 as heterogeneous photocatalysts
    Autor
    Rodrigues, Ana Sofia
    Ciríaco, Lurdes
    Pacheco, Maria José
    Fernandes, Annabel
    Mogo, Sandra
    Lopes, Ana
    Año del Documento
    2021
    Editorial
    MDPI
    Descripción
    Producción Científica
    Documento Fuente
    Nanomaterials, 2021, Vol. 11, Nº. 11, 3142
    Resumen
    Perovskites of the (La,Ba)(Fe,Ti)O3 family were prepared, characterized, and utilized as heterogeneous photocatalysts, activated by natural sunlight, for environmental remediation of Acid Orange 7 (AO7) aqueous solutions. Catalysts were prepared by the ceramic (CM) and the complex polymerization (CP) methods and characterized by XRD, SEM, EDS, and band gap energy. It was found that catalytic properties depend on the synthesis method and annealing conditions. In the photocatalytic assays with sunlight, different AO7 initial concentrations and perovskite amounts were tested. During photocatalytic assays, AO7 and degradation products concentrations were followed by HPLC. Only photocatalysis with BaFeO3-CM and BaTiO3-CP presented AO7 removals higher than that observed for photolysis. However, photolysis leads to the formation of almost exclusively amino-naphthol and sulfanilic acid, whereas some of the perovskites utilized form less-toxic compounds as degradation products, such as carboxylic acids (CA). Partial substitution of Ba by La in BaTiO3-CM does not produce any change in the photocatalytic properties, but the replacement of Ti by Fe in the La0.1Ba0.9TiO3 leads to reduced AO7 removal rate, but with the formation of CAs. The best AO7 removal (92%) was obtained with BaFeO3-CM (750 mg L−1), after 4 h of photocatalytic degradation with solar radiation.
    Materias (normalizadas)
    Perovskite
    Photocatalysis
    Solar light
    Polymerization
    Palabras Clave
    AO7
    Ceramic method
    ISSN
    2079-4991
    Revisión por pares
    SI
    DOI
    10.3390/nano11113142
    Patrocinador
    Fundação para a Ciência e a Tecnologia (FCT) (Project UIDB/00195/2020 and Grant SFRH/BD/109901/ 2015)
    Version del Editor
    https://www.mdpi.com/2079-4991/11/11/3142
    Propietario de los Derechos
    © 2021 The authors
    Idioma
    eng
    URI
    https://uvadoc.uva.es/handle/10324/59102
    Tipo de versión
    info:eu-repo/semantics/publishedVersion
    Derechos
    openAccess
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    • DEP31 - Artículos de revista [166]
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    Universidad de Valladolid

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