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Title: Formal Gold to Gold Transmetalation of an Alkynyl Group Mediated by Palladium: A Bisalkynyl Gold Complex as a Ligand to Palladium
Authors: Toledo Pérez, Alberto
Isabel Meana
Albéniz Jiménez, Ana Carmen
Issue Date: 2015
Publisher: American Chemical Society
Description: Producción Científica
Citation: Chemistry - A European Journal, 2015, Volume 21, Issue 38, p. 13216–13220
Abstract: The reaction of [Au(C≡CnBu)]n with [Pd(η3-allyl)Cl(PPh3)] results in a ligand and alkynyl rearrangement, and leads to the heterometallic complex [Pd(η3-allyl){Au(C≡CnBu)2}]2 (3) with an unprecedented bridging bisalkynyl gold ligand coordinated to palladium. This is a formal gold to gold transmetalation that occurs through reversible alkynyl transmetalations between gold and palladium.
Keywords: Palladium
ISSN: 2155-5435
Peer Review: SI
DOI: 10.1021/acscatal.6b01825
Sponsor: Ministerio de Economía, Industria y Competitividad (CTQ2013-48406-P)
Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA064U13)
Language: eng
Rights: info:eu-repo/semantics/openAccess
Appears in Collections:CINQUIMA - Artículos de revista
DEP63 - Artículos de revista

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