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Title: The Nucleoside Uridine Isolated in the Gas Phase
Authors: Peña, Isabel
Cabezas, Carlos
Alonso Hernández, José Luis
Issue Date: 2015
Publisher: Wiley Online Library
Citation: Angewandte Chemie International Edition, 2015 Mar 2;54(10), p. 2991-2994
Abstract: Herein we present the first experimental observation of the isolated nucleoside uridine, placed in the gas phase by laser ablation and characterized by Fourier transform (FT) microwave techniques. Free from the bulk effects of their native environments, anti/C2′-endo-g+ conformation has been revealed as the most stable form of uridine. Intramolecular hydrogen bonds involving uracil and ribose moieties have been found to play an important role in the stabilization of the nucleoside.
Peer Review: SI
DOI: 10.1002/anie.201412460
Publisher Version:
Rights Owner: 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Language: eng
Rights: info:eu-repo/semantics/restrictedAccess
Appears in Collections:DEP63 - Artículos de revista

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