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| dc.contributor.author | Pérez Iglesias, María | |
| dc.contributor.author | Lozano Lavilla, Olmo | |
| dc.contributor.author | Casares González, Juan Ángel | |
| dc.date.accessioned | 2019-10-03T10:34:02Z | |
| dc.date.available | 2019-10-03T10:34:02Z | |
| dc.date.issued | 2019 | |
| dc.identifier.citation | Organometallics, 2019, 38, 739–742 | es |
| dc.identifier.issn | 0276-7333 | es |
| dc.identifier.uri | http://uvadoc.uva.es/handle/10324/38346 | |
| dc.description.abstract | The copper compound [Cu(C6Cl2F3)(tht)]4 (1) (tht: tetrahydrothiophene) is an excellent catalyst for the trans-to-cis isomerization of complexes [PdAr2(tht)2](Ar: fluoroaryl) and also for the exchange of aryls between those palladium complexes. Herein, we also communicate the synthesis and characterization of 1 and some of its derivatives. The X-ray structure of 1 shows a linear chain of copper atoms, supported by fluoroaryl rings. The nuclear magnetic resonance 19F diffusion-ordered spectroscopy study indicates that this structure is preserved in solution, although it is in equilibrium with other species. | es |
| dc.format.mimetype | application/pdf | es |
| dc.language.iso | spa | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.title | [Cu(C6Cl2F2)(tht)]4: An Extremely Efficient Catalyst for the Aryl Scrambling between Palladium Complexes | es |
| dc.type | info:eu-repo/semantics/article | es |
| dc.identifier.doi | 10.1021/acs.organomet.8b00885 | es |
| dc.identifier.publicationfirstpage | 739 | es |
| dc.identifier.publicationissue | 4 | es |
| dc.identifier.publicationlastpage | 742 | es |
| dc.identifier.publicationtitle | Organometallics | es |
| dc.identifier.publicationvolume | 38 | es |
| dc.peerreviewed | SI | es |
| dc.identifier.essn | 1520-6041 | es |
| dc.type.hasVersion | info:eu-repo/semantics/draft | es |
