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dc.contributor.author | Pablo Nisa, Laura de | |
dc.contributor.author | Segovia Puras, José Juan | |
dc.contributor.author | Martín Martínez, Ángel | |
dc.contributor.author | Martín González, María del Carmen | |
dc.contributor.author | Bermejo Roda, Maria Dolores | |
dc.date.accessioned | 2019-07-25T11:46:27Z | |
dc.date.available | 2019-07-25T11:46:27Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | The Journal of Chemical Thermodynamics Volume 123, August 2018, Pages 185-194 | es |
dc.identifier.issn | 0021-9614 | es |
dc.identifier.uri | http://uvadoc.uva.es/handle/10324/37281 | |
dc.description | Producción Científica | es |
dc.description.abstract | In this work, densities, viscosities and vapor pressures of dimethyl sulfoxide (DMSO) + 1-allyl-3-methylimidazolium chloride (AmimCl) mixtures have been experimentally determined. Densities and viscosities were measured at temperatures T = [293.15, 373.15] K and molar fractions of dimethyl sulfoxide xDMSO = 0, 0.05, 0.1, 0.15, 0.25, 0.5, 0.75, 0.9 and 1 at atmospheric pressure with a Stabinger densimeter-viscosimeter. Viscosities and densities were found to decrease with increasing temperature and DMSO concentrations. Correlation of viscosity was made as a function of temperature and concentration with two modifications of the Seddon and Grunberg-Nissan equation, one with an average relative deviation of 6.8% and the second one of 16.3%. Vapor pressures of the mixtures were measured at T = [353.1, 433.1] K. and were correlated with Non-Random-Two-Liquid (NRTL) model, obtaining ARD% between 5 and 12%. | es |
dc.format.mimetype | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.subject | Propiedades físicas | es |
dc.subject.classification | Ionic liquidViscosityVapor pressureCorrelation | es |
dc.title | Determination of density, viscosity and vapor pressures of mixtures of dimethyl sulfoxide + 1-allyl-3-methylimidazolium chloride at atmospheric pressure | es |
dc.type | info:eu-repo/semantics/article | es |
dc.rights.holder | Elsevier | es |
dc.identifier.doi | https://doi.org/10.1016/j.jct.2018.04.014 | es |
dc.relation.publisherversion | https://doi.org/10.1016/j.jct.2018.04.014 | es |
dc.identifier.publicationfirstpage | 185 | es |
dc.identifier.publicationissue | 123 | es |
dc.identifier.publicationlastpage | 194 | es |
dc.identifier.publicationtitle | The Journal of Chemical Thermodynamics | es |
dc.identifier.publicationvolume | 123 | es |
dc.peerreviewed | SI | es |
dc.description.project | Junta de Castilla y León, proyecto VA295U14 | es |
dc.description.project | MINECO proyecto ENE2014-53459-R | es |
dc.description.project | MINECO Prorama Ramón y Cajal RYC-2013-13976 | es |
dc.type.hasVersion | info:eu-repo/semantics/draft | es |