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Title: The stille reaction, 38 years later
Authors: Cordovilla, Carlos
Bartolomé Albistegui, María del Camino
Martínez de Ilarduya, Jesús María
Espinet Rubio, Pablo
Issue Date: 2015
Publisher: American Chemical Society
Description: Producción Científica
Citation: ACS Catalysis 2015, 5 (5), p. 3040–3053
Abstract: The first now named Stille reaction was published 38 years ago, and the last comprehensive revision of this catalysis was in 2004. Since then the knowledge of the different steps of the three possible (and sometimes competing) reaction pathways (cyclic, open, and ionic) has been almost completed by synergistic experimental and theoretical studies: the Stille reaction is perhaps the best characterized catalytic process if we consider the number of intermediates that have been detected. This review concentrates on the mechanistic new knowledge, and on important aspects as the revolution with the use of bulky phosphines, the bimetallic alternative of the Stille reaction, the enantioselectivity in Stille and palladium free Stille processes, the meaning of copper effect, or the possible approaches to make Stille coupling a greener process.
Keywords: Stille cross-coupling
ISSN: 2155-5435
Peer Review: SI
DOI: 10.1021/acscatal.5b00448
Sponsor: Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. GR 169 and VA256U13)
Ministerio de Economía, Industria y Competitividad (CTQ2013-48406-P)
Language: eng
Rights: info:eu-repo/semantics/openAccess
Appears in Collections:CINQUIMA - Artículos de revista
DEP63 - Artículos de revista

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