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Title: Prediction of single salt rejection in nanofiltration membranes by independent measurements
Authors: Silva, Verónica
Montalvillo, Miguel
Carmona, Francisco Javier
Palacio Martínez, Laura
Hernández Giménez, Antonio
Prádanos del Pico, Pedro
Issue Date: 2016
Publisher: Elsevier
Description: Producción Científica
Citation: Desalination 2016, vol. 382, p. 1–12
Abstract: In this work amethod is proposed to predict salt rejection by nanofiltration. The procedure starts fromthe steric, electric and dielectric exclusion model with charge (and permitivity) depending on the concentration along the pore, SEDE-VCh, for membrane characterization, and substitutes all fitting parameters by values obtained by independent methods. These parameters are the relative permittivity inside the pores and the two constants of the Freundlich isothermfor the volumetric charge density,which can be obtained by impedance spectroscopy techniques. Moreover, the pore size and shape and the active layer thickness are required to complement the model. The pore size was obtained by using a neutral solute rejection test and the active layer thickness was estimated by SEM. Therefore, the model also requires pore shape as input. AFM measurements suggest the assumption of a slit shape for the pores. A Desal-HL membrane has been structurally, electrically and functionally characterized. These data allowed the testing of the predictive model that was subsequently demonstrated; as far as results are good enough considering the complexity of the mechanisms involved. Consequently, it seems clear that once the model parameters have been obtained by independent methods, it can be used as a predictive tool.
Keywords: Impedance spectroscopy
Membrane potential
Transport numbers
Dielectric properties
ISSN: 0011-9164
Peer Review: SI
DOI: 10.1016/j.desal.2015.12.012
Sponsor: Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA302U13)
Publisher Version:
Language: eng
Rights: info:eu-repo/semantics/openAccess
Appears in Collections:DEP31 - Artículos de revista

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