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Please use this identifier to cite or link to this item: http://uvadoc.uva.es/handle/10324/29152
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dc.contributor.authorÁlvarez González, Celedonio-
dc.contributor.authorGarcía Rodríguez, Raúl-
dc.contributor.authorMiguel San José, Daniel-
dc.date.accessioned2018-03-19T12:23:42Z-
dc.date.available2018-03-19T12:23:42Z-
dc.date.issued2016-
dc.identifier.citationDalton Transactions 2016, 45 , pp. 963 – 972es
dc.identifier.issn1477-9226es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/29152-
dc.descriptionProducción Científicaes
dc.description.abstractMetallamacrocycles of 12, 16, and 22 members are obtained by deprotonation of the carboxylic group of the side chain of iminopyridine complexes derived from the amino acid β-alanine, and the peptides Gly–Gly and Gly–Gly–Gly. Instead of the expected intramolecular attack to give tridentate (N,N,O) ligands, the deprotonated carboxylate attacks in an inter-molecular manner to give dimers in which the ligand acts as a bridge bonded in a κ2(N,N′) chelating fashion to one metal and as κ(O) to the other metal. The formation of the dimers is supported by NMR spectroscopy, mass spectrometry and X-ray crystallography.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.subject.classificationMetallamacrocyclees
dc.titleMetallamacrocycle formation through dimerization of metal bioconjugates derived from amino acids and peptideses
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1039/C5DT01256Bes
dc.relation.publisherversionhttp://pubs.rsc.org/en/content/articlelanding/2016/dt/c5dt01256b#!divAbstractes
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (Project CTQ2013-41067-P)es
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