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Title: α-Substituted Benzylic Complexes of Palladium(II) as Precursors of Palladium Hydrides
Authors: Martín Ruiz, Blanca
Pérez Ortega, Ignacio
Albéniz Jiménez, Ana Carmen
Issue Date: 2018
Publisher: American Chemical Society
Citation: Organometallics, 2018, vol. 37, p. 1665-1670
Abstract: The adoption of a pseudoallylic (η3) form makes palladium benzylic derivatives a class of stabilized palladium alkyls that can undergo β-H elimination reactions in a more controlled way. α- (Pentafluorophenylmethyl)benzyl palladium complexes have been studied and they decompose by β-H elimination to give palladium hydrides that, depending on the auxil- iary ligands can: a) transmetalate to another palladium atom and, by reductive elimina- tion, give hydrogenated products; this process is favored for a combination of bridging ligands (i.e halogens) and low coordinating ligands. b) Be used as a hydride source and get trapped by a diene to give palladium allylic derivatives. The presence of carbon mon- oxide does not induce a β-H elimination reactions and only CO insertion into the Pd- benzyl bond to give acyl derivatives is observed.
Keywords: Chemistry
Organometallic Chemistry
Classification: Palladium
Benzyl complexes
Peer Review: SI
DOI: 10.1021/acs.organomet.8b00066
Sponsor: MINECO (SGPI, grant CTQ2016-80913-P)
Publisher Version:
Language: eng
Rights: info:eu-repo/semantics/openAccess
Appears in Collections:DEP63 - Artículos de revista
CINQUIMA - Artículos de revista

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