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dc.contributor.authorPablo Nisa, Laura de
dc.contributor.authorSánchez, Francisco A.
dc.contributor.authorBermejo Roda, Maria Dolores 
dc.contributor.authorPereda, Selva
dc.date.accessioned2019-07-25T12:02:03Z
dc.date.available2019-07-25T12:02:03Z
dc.date.issued2019
dc.identifier.citationFluid Phase Equilibria Volume 479, 15 January 2019, Pages 25-32es
dc.identifier.issn0378-3812es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/37283
dc.descriptionProducción Científicaes
dc.description.abstractIn this work, the Group Contribution Equation of State (GC-EoS) is extended to model two new ionic liquid families, namely, 1-alkyl-3-methylimidazolium dimethylphosphate ([-MeIm]+[Me2PO4]-) and 1-alkyl-3-methylimidazolium diethylphosphate ([-MeIm]+[Et2PO4]-). Pure group parameters for the functional groups [-MeIm]+[Me2PO4]- and [-MeIm]+[Et2PO4]- and interaction parameters between these groups and the main paraffinic and aromatic subgroups (CH3, CH2, ACH, AC, ACCH3, CH2=CH) were estimated using infinite dilution activity coefficients from literature. In order to evaluate the performance of the new parameters, the model was compared with experimental data on the phase behavior of binary mixtures, showing an average relative deviation of 4.5%.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherElsevieres
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.subject.classificationIonic liquidsGroup contributionEquation of state1-alkyl-3-methylimidazolium dimethylphosphate1-alkyl-3-methylimidazolium diethylphosphateGC-EoSes
dc.titleGC-EoS extension to alkylphosphate imidazolium ionic liquidses
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holderElsevieres
dc.identifier.doihttps://doi.org/10.1016/j.fluid.2018.09.022es
dc.relation.publisherversionhttps://doi.org/10.1016/j.fluid.2018.09.022es
dc.identifier.publicationfirstpage25es
dc.identifier.publicationlastpage32es
dc.identifier.publicationtitleFluid Pahse Equilibriaes
dc.identifier.publicationvolume479es
dc.peerreviewedSIes
dc.description.projectMINECO proyecto ENE2014-53459-Res
dc.description.projectMINECO Prorama Ramón y Cajal RYC-2013-13976es
dc.description.projectConsejo Nacional de Investigaciones Científicas y Técnicas (PIP 112 2015 010 856)es
dc.description.projectMinisterio de Ciencia, Tecnología e Innovación Productiva (PICT 2016 0907)es
dc.description.projectUniversidad Nacional del Sur (PGI - 24/M133)es
dc.description.projectLP thanks the Erasmus Mundus Euricaes
dc.type.hasVersioninfo:eu-repo/semantics/draftes


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