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dc.contributor.author | Pablo Nisa, Laura de | |
dc.contributor.author | Sánchez, Francisco A. | |
dc.contributor.author | Bermejo Roda, Maria Dolores | |
dc.contributor.author | Pereda, Selva | |
dc.date.accessioned | 2019-07-25T12:02:03Z | |
dc.date.available | 2019-07-25T12:02:03Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Fluid Phase Equilibria Volume 479, 15 January 2019, Pages 25-32 | es |
dc.identifier.issn | 0378-3812 | es |
dc.identifier.uri | http://uvadoc.uva.es/handle/10324/37283 | |
dc.description | Producción Científica | es |
dc.description.abstract | In this work, the Group Contribution Equation of State (GC-EoS) is extended to model two new ionic liquid families, namely, 1-alkyl-3-methylimidazolium dimethylphosphate ([-MeIm]+[Me2PO4]-) and 1-alkyl-3-methylimidazolium diethylphosphate ([-MeIm]+[Et2PO4]-). Pure group parameters for the functional groups [-MeIm]+[Me2PO4]- and [-MeIm]+[Et2PO4]- and interaction parameters between these groups and the main paraffinic and aromatic subgroups (CH3, CH2, ACH, AC, ACCH3, CH2=CH) were estimated using infinite dilution activity coefficients from literature. In order to evaluate the performance of the new parameters, the model was compared with experimental data on the phase behavior of binary mixtures, showing an average relative deviation of 4.5%. | es |
dc.format.mimetype | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.subject.classification | Ionic liquidsGroup contributionEquation of state1-alkyl-3-methylimidazolium dimethylphosphate1-alkyl-3-methylimidazolium diethylphosphateGC-EoS | es |
dc.title | GC-EoS extension to alkylphosphate imidazolium ionic liquids | es |
dc.type | info:eu-repo/semantics/article | es |
dc.rights.holder | Elsevier | es |
dc.identifier.doi | https://doi.org/10.1016/j.fluid.2018.09.022 | es |
dc.relation.publisherversion | https://doi.org/10.1016/j.fluid.2018.09.022 | es |
dc.identifier.publicationfirstpage | 25 | es |
dc.identifier.publicationlastpage | 32 | es |
dc.identifier.publicationtitle | Fluid Pahse Equilibria | es |
dc.identifier.publicationvolume | 479 | es |
dc.peerreviewed | SI | es |
dc.description.project | MINECO proyecto ENE2014-53459-R | es |
dc.description.project | MINECO Prorama Ramón y Cajal RYC-2013-13976 | es |
dc.description.project | Consejo Nacional de Investigaciones Científicas y Técnicas (PIP 112 2015 010 856) | es |
dc.description.project | Ministerio de Ciencia, Tecnología e Innovación Productiva (PICT 2016 0907) | es |
dc.description.project | Universidad Nacional del Sur (PGI - 24/M133) | es |
dc.description.project | LP thanks the Erasmus Mundus Eurica | es |
dc.type.hasVersion | info:eu-repo/semantics/draft | es |