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    • Dpto. Electricidad y Electrónica
    • DEP22 - Artículos de revista
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    Por favor, use este identificador para citar o enlazar este ítem:https://uvadoc.uva.es/handle/10324/64851

    Título
    Understanding the color change of the solutions of Cp2TiCl upon addition of water
    Autor
    Thiessen, Tanner
    Sidhu, Jaspreet
    McIndoe, J. Scott
    Rodríguez‐García, Ignacio
    Rosales Martínez, Antonio
    Jaraíz Maldonado, MartínAutoridad UVA Orcid
    Enríquez Giraudo, María LourdesAutoridad UVA
    mcindoe
    Año del Documento
    2022
    Editorial
    Wiley
    Descripción
    Producción Científica
    Documento Fuente
    Appl Organomet Chem.2023;37:c6979
    Abstract
    Reduction of red bis (cyclopentadienyl)titanium (IV) dichloride (Cp2TiCl2)with manganese dust in dry THF produces a green solution that turns deepblue upon the addition of traces of water. Mass spectrometric analysis andDFT calculations have been performed to achieve a better understanding ofthe species that may be present after the interaction of water with reducedCp2TiCl2. The deep blue solution provides a handy visual indicator for thequalitative determination of water in THF
    Palabras Clave
    hydrogen atom transfer reagent
    radic
    colorimetric indicator
    radical chemistry
    titanocede
    ISSN
    0268-2605
    Revisión por pares
    SI
    DOI
    10.1002/aoc.6979
    Patrocinador
    University of Sevilla, Grant/Award Numbers: 2021/00000422, 2020/00001014; University of Almería; Junta de Andalucía; Fondo Europeo de Desarrollo Regional (FEDER), Grant/Award Number: UAL2020-FQM-B1989
    Version del Editor
    https://doi.org/10.1002/aoc.6979
    Propietario de los Derechos
    © 2022 The Authors.Applied Organometallic Chemistrypublished by John Wiley
    Idioma
    eng
    URI
    https://uvadoc.uva.es/handle/10324/64851
    Tipo de versión
    info:eu-repo/semantics/publishedVersion
    Derechos
    openAccess
    Collections
    • DEP22 - Artículos de revista [65]
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    Attribution-NonCommercial-NoDerivatives 4.0 InternacionalExcept where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 Internacional

    Universidad de Valladolid

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