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    • SCIENTIFIC PRODUCTION
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    • Dpto. Química Orgánica
    • DEP67 - Artículos de revista
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    Por favor, use este identificador para citar o enlazar este ítem:https://uvadoc.uva.es/handle/10324/76255

    Título
    Towards an efficient methodology for the synthesis of functionalized dihydropyrans by silyl-Prins cyclization: access to truncated natural products
    Autor
    Fernández Peña, LauraAutoridad UVA Orcid
    González-Andrés, PaulaAutoridad UVA
    Barbero, Asunción
    Año del Documento
    2024
    Editorial
    RSC
    Documento Fuente
    RSC Adv., 2024, 14, 707–711
    Abstract
    We herein present a selective methodology for the synthesis of disubstituted dihydropyrans by silyl-Prins cyclization of Z-vinylsilyl alcohols mediated by trimethylsilyl trifluoromethanesulfonate (TMSOTf). The reaction features broad substrate scope, short reaction times and ease of process scale-up. Moreover, to showcase the applicability of the proposed method, we also report a facile and linear synthesis of analogues of rhopaloic acid and natural doremox fragrance.
    Revisión por pares
    SI
    DOI
    10.1039/d3ra07520f
    Idioma
    eng
    URI
    https://uvadoc.uva.es/handle/10324/76255
    Tipo de versión
    info:eu-repo/semantics/draft
    Derechos
    openAccess
    Collections
    • DEP67 - Artículos de revista [55]
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    Universidad de Valladolid

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